全文获取类型
收费全文 | 1724篇 |
免费 | 73篇 |
国内免费 | 8篇 |
专业分类
电工技术 | 104篇 |
综合类 | 6篇 |
化学工业 | 578篇 |
金属工艺 | 70篇 |
机械仪表 | 51篇 |
建筑科学 | 48篇 |
能源动力 | 120篇 |
轻工业 | 160篇 |
水利工程 | 1篇 |
石油天然气 | 2篇 |
无线电 | 91篇 |
一般工业技术 | 340篇 |
冶金工业 | 19篇 |
原子能技术 | 52篇 |
自动化技术 | 163篇 |
出版年
2023年 | 17篇 |
2022年 | 5篇 |
2021年 | 62篇 |
2020年 | 30篇 |
2019年 | 21篇 |
2018年 | 34篇 |
2017年 | 40篇 |
2016年 | 56篇 |
2015年 | 32篇 |
2014年 | 63篇 |
2013年 | 143篇 |
2012年 | 91篇 |
2011年 | 133篇 |
2010年 | 99篇 |
2009年 | 136篇 |
2008年 | 110篇 |
2007年 | 94篇 |
2006年 | 77篇 |
2005年 | 84篇 |
2004年 | 68篇 |
2003年 | 65篇 |
2002年 | 48篇 |
2001年 | 24篇 |
2000年 | 27篇 |
1999年 | 27篇 |
1998年 | 23篇 |
1997年 | 17篇 |
1996年 | 23篇 |
1995年 | 21篇 |
1994年 | 19篇 |
1993年 | 21篇 |
1992年 | 6篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1989年 | 10篇 |
1988年 | 10篇 |
1987年 | 3篇 |
1986年 | 8篇 |
1985年 | 4篇 |
1984年 | 8篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1975年 | 2篇 |
1973年 | 4篇 |
1972年 | 2篇 |
排序方式: 共有1805条查询结果,搜索用时 15 毫秒
51.
Shohei Ueta Jun AiharaKazuhiro Sawa Atsushi YasudaMasaki Honda Noboru Furihata 《Progress in Nuclear Energy》2011,53(7):788-793
This paper describes experiences and present status of research and development works for the high temperature gas-cooled reactor (HTGR) fuel in Japan. Recently, Very High Temperature Reactor (VHTR) is evaluated highly worldwide, and is a principal candidate for the Generation IV reactor systems. In Japan, HTGR fuel fabrication technologies have been developed through the High Temperature Engineering Test Reactor (HTTR) project in Japan Atomic Energy Agency since 1960’s. In total about 2 tons of uranium of the HTTR fuel has been fabricated successfully and its excellent quality has been confirmed through the long-term high temperature operation. Based on the HTTR fuel technologies, SiC TRISO fuel has been newly developed for burnup extension targeted VHTR. For ZrC-TRISO coated fuel as an advanced fuel designs, R&Ds for fabrication and inspection have been carried out in JAEA. The irradiation with the Japanese uniform stoichiometric ZrC coating has been completed in the cooperation with Oak Ridge National Laboratory of the United States. 相似文献
52.
Kazuyuki Yagi Yukito Ebisu Joichi Sugimura Seiji Kajita Toshihide Ohmori Atsushi Suzuki 《Tribology Letters》2011,43(3):361-368
In this study, a direct observation of a point contact area was conducted to understand the scuffing phenomenon. The contact
area was produced between a rotating sapphire disc and a stationary steel ball and it was lubricated using n-hexadecane. The image detected by a colour digital CCD camera, load, and friction were synchronously recorded by a computer
during the test. It was found that wear debris produced in the contact area played an important role in the wear process,
which includes running-in and scuffing. In the test, debris particles accumulated in the inlet zone, and some particles entered
the contact area to cause abrasive wear of the ball surface, even in the light-load stages. During the running-in process,
the abrasive wear by debris particles changed the conformity between the sliding surfaces. In the high-load stage, just before
the occurrence of scuffing, the whole contact area was flattened at once. When scuffing occurred, the contact area suddenly
expanded. The conformity of the contact area was dramatically changed during its expansion. The flattening of the whole contact
area and dramatic expansion with changing the conformity seemed to play important roles in scuffing. 相似文献
53.
54.
Crevice corrosion of four kinds of stainless steel, SUS316L, NAS64, NAS185N and NAS254N, in saturated NaCl solution at temperatures up to 100 °C was investigated using the multichannel electrode method. In this method, a pile of five individual working electrodes (WEs) of stainless steel sheet were embedded in epoxy resin and a small hole penetrating through the five WEs was treated as an artificial crevice. Time transition and distribution of the coupling current between the five WEs were measured as a function of crevice depth, kind of stainless steel, temperature and concentration of dissolved oxygen (DO). Anodic or cathodic coupling current on the five WEs of SUS316L changed depending on their corroding state. On the other hand, NAS64, NAS185N and NAS254N showed that the WE outside the crevice contributed as a cathode and that WEs inside the crevice contributed as an anode. The coupling current on SUS316L was strongly affected by concentration of DO, while the coupling current on NAS64, NAS185N and NAS254N was not affected by DO, probably due to the establishment of a passive state inside the crevice. 相似文献
55.
Meng-Liang Lin Kenji Hara Yasuhiro Okubo Masaaki Yanagi Hironobu Nambu Atsushi Fukuoka 《Catalysis communications》2011,12(13):1228-1230
The olefin epoxidation is one of the most important reactions in chemical industry. Metal oxide supports often cause drawbacks in catalytic activity and selectivity, which has been overcome by introducing hydrophobic organic groups onto the oxide supports. The present study utilizes ordered mesoporous carbon (CMK-3 and CMK-1) as structurally defined hydrophobic catalyst support. Well-dispersed tantalum oxides supported on the ordered mesoporous carbon were prepared. Their application in catalytic epoxidation of cyclooctene demonstrates that the tantalum oxide catalysts on the ordered mesoporous carbon supports show higher performances than those of the catalysts supported on activated carbon and ordered mesoporous silica SBA-15. 相似文献
56.
Complex hydrides have energy storage‐related functions such as i) solid‐state hydrogen storage, ii) electrochemical Li storage, and iii) fast Li‐ and Na‐ionic conductions. Here, recent progress on the development of fast Li‐ionic conductors based on the complex hydrides is reported. The validity of using them as electrolytes in all‐solid‐state lithium rechargeable batteries is also examined. Not only coated oxides but also bare sulfides are found to be applicable as positive electrode active materials. Results related to fast Na‐ionic conductivity in the complex hydrides are presented. In the last section, the future prospects for battery assemblies with high‐energy densities, and Mg ion batteries with the liquid and the solid‐state electrolytes are discussed. 相似文献
57.
Pawel E. Malinowski Atsushi Nakamura Dimitri Janssen Yoshitaka Kamochi Ichiro Koyama Yu Iwai Anna Stefaniuk Ewelina Wilenska Caterin Salas Redondo David Cheyns Soeren Steudel Paul Heremans 《Organic Electronics》2014,15(10):2355-2359
We report on the fabrication of organic photodetectors (OPD) based on isolated islands of P3HT:PCBM. Pattern transfer to the active material was done with photolithography based on non-fluorinated solvents and the excessive organic semiconductor was removed with oxygen plasma reactive ion etching. The photoresist system used was found to be benign to the P3HT:PCBM layer as confirmed by absorption, thickness and roughness measurements. Current–voltage characteristics and external quantum efficiency (EQE) remained unchanged after the patterning process. It was demonstrated that it is possible to photolithographically pattern isolated islands with 200 μm edge length with the same dark current density (<10−5 A/cm2 at −2 V bias voltage) and photocurrent density (>5 × 10−3 A/cm2 at −2 V). Furthermore, concerning the solar cell performance, the patterned, small-area devices showed power conversion efficiency of 2.1% and fill-factor of 60%. Dark current was observed to depend on the size of the remaining semiconductor island, which was demonstrated on OPDs with diameter of 50 μm. The presented results show the feasibility of fabrication of isolated devices based on organic semiconductors patterned with non-fluorinated photolithography. 相似文献
58.
Masatoshi Hasegawa Mari Fujii Junichi Ishii Shinya Yamaguchi Eiichiro Takezawa Takashi Kagayama Atsushi Ishikawa 《Polymer》2014
A novel cycloaliphatic monomer for polyimides (PI), 1S,2S,4R,5R-cyclohexanetetracarboxylic dianhydride (H′-PMDA) is proposed in this work. H′-PMDA shows high polymerizability with various diamines in contrast to its isomer, i.e., conventional hydrogenated pyromellitic dianhydride (H-PMDA) and leads to highly flexible and colorless PI films with very high Tg's. In particular, the combinations with rigid structures of diamines give rise to PIs with significantly decreased coefficients of thermal expansion (CTE) owing to high extents of in-plane chain orientation induced by thermal imidization, whereas the H-PMDA-based counterparts do not. The decreased CTE reflects structural rigidity/linearity of the H′-PMDA-based diimide units as supported by liquid crystallinity observed in the corresponding model compound. Solution casting of a chemically imidized PI derived from H′-PMDA and 2,2′-bis(trifluoromethyl)benzidine (TFMB) results in a lower CTE than that of the thermally imidized counterpart, suggesting the presence of a self-orientation phenomenon during solvent evaporation. The mechanism is proposed in this work. H′-PMDA/TFMB and its copolymer systems can be useful as plastic substrates in image display devices and/or novel coating-type optical compensation films. 相似文献
59.
Koji Honda Ikuo Yamamoto Masamichi Morita Hiroki Yamaguchi Hiroshi Arita Ryohei Ishige Yuji Higaki Atsushi Takahara 《Polymer》2014
The effect of α-substituent on the molecular motion and wetting behavior of poly{2-(perfluorobutyl)ethyl acrylate} [PFA-C4], poly{2-(perfluorobutyl)ethyl methacrylate} [PFMA-C4], poly{2-(perfluorobutyl)ethyl α-fluoroacrylate} [PFFA-C4], and poly{2-(perfluorobutyl)ethyl α-chloroacrylate} [PFClA-C4] films were characterized by dynamic contact angle measurement, lateral force microscopy (LFM), wide angle X-ray diffraction (WAXD), and X-ray photoelectron spectroscopy (XPS). WAXD of oriented PFClA-C4 fiber suggested the presence of rod-like chain due to the presence of bulky α-substituent. The glass transition temperature (Tg) of PFFA-C4 and PFClA-C4 were well above the room temperature. The water repellencies of PFFA-C4 and PFClA-C4 were as high as that of PFMA-C4 and their oil repellency of PFFA-C4 and PFClA-C4 was higher than the PFMA-C4. This result was originated from the low main chain mobility of PFFA-C4 and PFClA-C4 due to the presence of bulky α-substituents. The effect of molecular motion on water repellency was clarified by the results of temperature dependence studies of dynamic contact angle, LFM, and surface chemical composition measured by XPS. 相似文献
60.
Koshi Takenaka Masayoshi Ichigo Taisuke Hamada Atsushi Ozawa Takashi Shibayama Tetsuya Inagaki 《Science and Technology of Advanced Materials》2014,15(1)
Magnetostructural correlations in antiperovskite manganese nitrides were investigated systematically for stoichiometric and solid solution Mn3Cu1?xAxN (A = Co, Ni, Zn, Ga, Ge, Rh, Pd, Ag, In, Sn or Sb). This class of nitrides is attracting great attention because of their giant negative thermal expansion, which is achieved by doping Ge or Sn into the A site as a relaxant of the sharp volume contraction on heating (spontaneous volume magnetostriction ωs) because of the magnetovolume effects. The physical background of large ωs and mechanism of how the volume contraction becomes gradual with temperature are central concerns for the physics and applications of these nitrides. An entire dataset of thermal expansion, crystal structure and magnetization demonstrates that the cubic triangular antiferromagnetic state is crucial for large ωs. The intimate relationship between ωs and the magnetic structure is discussed in terms of geometrical frustration related to the Mn6N octahedron and magnetic stress concept. The results presented herein also show that ωs depends on the number of d electrons in the A atom, suggesting the important role of the d orbitals of the A atom. Not all the dopants in the A site, but the elements that disturb the cubic triangular antiferromagnetic state, are effective in broadening the volume change. This fact suggests that instability neighboring the phase boundary is related to the broadening. The relation between the gradual volume change and the local structure anomaly is suggested by recent microprobe studies. 相似文献